Opening the Analytical Black Box: Insights into Interferences, Corrections, and Data Quality

Abstract

GF-AAS is an old technique, but nevertheless useful and an important tool in the toolbox. Using standard ICP-AES emission wavelengths and known IEC is usually fine, but certain interferences require alternative correction methods, such as MSF. ICP-MS is has interferences that can t be corrected mathematically. Using standard isotopes and correction equations is generally fine, but at least monitor other isotopes and monitor with and without correction equations. Collision or Reaction Cell ICP-MS does not takes care of all other interferences in ICP-MS, but is a powerful tool if understood and used properly.

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Document Details

Document Type
Technical Report
Publication Date
Mar 29, 2012
Accession Number
ADA567383

Entities

People

  • Anthony J. Bednar
  • D. M. Sirkis
  • T. J. Kelly
  • W. E. Harris

Organizations

  • Engineer Research and Development Center

Tags

DTIC Thesaurus Topics

  • Abstracts
  • Army Corps Of Engineers
  • Atomization
  • Collisions
  • Elements
  • Environmental Monitoring
  • Equations
  • Gases
  • Information Operations
  • Ionization Potentials
  • Kinetic Energy
  • Monitoring
  • Rare Earth Elements
  • Reactive Gases
  • Standards
  • Suspended Sediments
  • Water

Readers

  • Analytical Chemistry
  • Approximation Theory.
  • Software Engineering.