Methyl Salicylate: A Reactive Chemical Warfare Agent Surrogate to Detect Reaction with Hypochlorite (POSTPRINT)

Abstract

Methyl Salicylate (MeS) has been widely used as a surrogate for the chemical agents GD and HD in tests such as vapor penetration because all three exhibit similar volatility. The chemistry of the same three chemicals is grossly dissimilar, and different surrogates --e.g., diisopropyl fluorophosphate for GD in challenges by a nucleophilic neutralizing agent, because both share the R-O-P-F functionality --are generally used for tests of reactivity with potential neutralizing agents. However, the phenolic -OH of MeS suggests oxidizability, which raised the possibility that MeS might function as a surrogate for examining the efficiency of coverage and distribution of a sprayed oxidizing agent as a neutralizing treatment.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
May 01, 2011
Accession Number
ADA568827

Entities

People

  • Jeffery R. Owens
  • Joseph D. Wander
  • Wallace B. Salter

Organizations

  • Applied Research Associates (United States)

Tags

Communities of Interest

  • Space

DTIC Thesaurus Topics

  • Acids
  • Air Force
  • Air Force Facilities
  • Air Force Research Laboratories
  • Alcohols
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemistry
  • Electrons
  • Mass Spectra
  • Mass Spectrometry
  • Military Research
  • Physical Properties
  • Spectra
  • Warfare

Readers

  • Analytical Chemistry