Steric Control of Complex Chemical Reactions - II

Abstract

The aim of this project is to understand and ultimately to stereo-control the reactive outcome of complex systems by vibrational excitations of reactants. The most exciting result during this period is the paper published in Nature Chemistry 4, 636-641 (2012). In that work, we reported the complete three-dimensional characterization of the sterics of a benchmark polyatomic reaction by measuring the dependence of the product state-resolved angular distributions on the spatial alignment of the reactive bond in a crossed molecular beam experiment. This is for the first time that a true three-dimensional view of the steric effects has been realized experimentally for any chemical reaction in the half century history of chemical dynamics. The results prove the existence of two distinct microscopic reaction mechanisms in the reaction of Cl + CHD3(v1=1) → HCl(v=0, 1) + CD3(00). Detailed analysis further reveals the origin of the stereodynamics in the HCl(v=0) + CD3(00) product channel can be captured by a textbook line-of-centres model. In contrast, a time-delay pathway, most likely mediated by reactive resonances, appears to be operative in forming the excited HCl(v=1) + CD3(00) product pair. The work received immediate attention upon publication, as highlighted by Science Editors? Choice under the title "Angle of Attack", in Science 337, 779 (2012).

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Document Details

Document Type
Technical Report
Publication Date
Dec 06, 2012
Accession Number
ADA570779

Entities

People

  • Kopin Liu

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Kinetics
  • Chemical Reactions
  • Chemistry
  • Complex Systems
  • Dynamics
  • Excitation
  • Femtosecond Lasers
  • Kinetics
  • Molecular Beams
  • Physical Chemistry
  • Resonance
  • Three Dimensional

Readers

  • Molecular Photonics/Laser Physics
  • Quantum Chemistry
  • Systems Analysis and Design