Formaldehyde Five-Day Passive Chemical Dosimeter Badge Validation Study

Abstract

The utility of commercially available chemical dosimeter badges to adequately sample low-concentration formaldehyde vapor aboard Navy submarines was evaluated. In this work, badges were exposed to formaldehyde vapor at two approximate concentrations: 6 ppb and 2.5 ppb (13% and 6% of the Navy 90-day exposure limit, respectively) and for durations of 30, 60, 90, and 120 hours. Certified permeation tubes were used to generate formaldehyde vapor, which was then validated by a reference method (NIOSH 2016) based on active sampling with sorbent tubes. Badges and cartridges spiked with known concentrations of formaldehyde demonstrated extraction efficiencies of 59.26% and 69.75%, respectively. In these tests, the chemical dosimeter badges exhibited a consistent uptake rate with respect to exposure (expressed in units of parts-per-billion hours) as would be predicted theoretically by Fick?s law of diffusion, indicating that they are effective at monitoring low-level concentrations of formaldehyde for extended sampling durations. The uptake rate was observed to be 0.002 micrograms of formaldehyde adsorbed per ppb hour.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Nov 30, 2012
Accession Number
ADA572545

Entities

People

  • Janet M. Hughes
  • Kevin Johnson

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Acetonitrile
  • Boats
  • Chemical Synthesis
  • Chemistry
  • Detection
  • Equations
  • Flow Rate
  • Formaldehyde
  • Liquid Chromatography
  • Navy
  • Nitriles
  • Nuclear Powered Submarines
  • Organic Chemistry
  • Organic Compounds
  • Potassium Compounds
  • Submarine Atmospheres
  • Submarines

Readers

  • Analytical Chemistry
  • Mathematics or Statistics
  • Nuclear and Radiation Engineering.