Enhanced Plasmon Coupling in Crossed Dielectric/metal Nanowire Composite Geometries and Applications to Surface-enhanced Raman Spectroscopy

Abstract

Surface-enhanced Raman spectroscopy (SERS) was performed on Ga2O3 /Ag and ZnO/Ag nanowires, which were arranged in either a crossover or noncrossing geometry. Results indicate a high SERS sensitivity (near 0.2 pg) for nanowires arranged in a crossing geometry. It is suggested that this is due to the dielectric core/metal shell structure, as well as to the nanowire crossings, which are regions of very high electric fields. Finite element simulations of the electric field near two crossed wires confirm an enhanced plasmon resonance in the vicinity of the crossing, which extends spatially in the crossings and around the nanowires.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 2007
Accession Number
ADA574008

Entities

People

  • Mario G. Ancona
  • O. J. Glembocki
  • R. W. Rendell
  • Sharka M. Prokes

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Compounds
  • Composite Materials
  • Couplings
  • Electric Fields
  • Geometry
  • Hot Spots
  • Materials
  • Nanoparticles
  • Nanostructures
  • Nanotechnology
  • Nanowires
  • Raman Scattering
  • Raman Spectroscopy
  • Resonance
  • Spectroscopy
  • Surface Plasmon Resonance
  • Three Dimensional

Fields of Study

  • Physics

Readers

  • Electrochemical Surface Science
  • Plasma Physics / Magnetohydrodynamics
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.