Chemical Detection with a Single-Walled Carbon Nanotube Capacitor

Abstract

We show that the capacitance of single-walled carbon nanotubes (SWNTs) is highly sensitive to a broad class of chemical vapors and that this transduction mechanism can form the basis for a fast, low-power sorption-based chemical sensor. In the presence of a dilute chemical vapor, molecular adsorbates are polarized by the fringing electric fields radiating from the surface of a SWNT electrode, which causes an increase in its capacitance. We use this effect to construct a high-performance chemical sensor by thinly coating the SWNTs with chemoselective materials that provide a large, class-specific gain to the capacitance response. Such SWNT chemicapacitors are fast, highly sensitive, and completely reversible.

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Document Details

Document Type
Technical Report
Publication Date
Mar 25, 2005
Accession Number
ADA574082

Entities

People

  • E. J. Houser
  • E. S. Snow
  • Frank Keith Perkins
  • Thomas L. Reinecke
  • Ştefan C. Bǎdescu

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Sensors

DTIC Thesaurus Topics

  • Capacitance
  • Capacitors
  • Carbon Nanotubes
  • Chemical Detection
  • Detection
  • Detectors
  • Dipole Moments
  • Electric Fields
  • Fullerenes
  • Materials
  • Materials Processing
  • Monomolecular Films
  • Organic Compounds
  • Physics Laboratories
  • Self Assembled Monolayers
  • Vapor Pressure
  • X Rays

Readers

  • Electromagnetic Wave Scattering and Antenna Radiation Engineering
  • Nanocomposite Materials Science