High-Performance Bio-Based Cyanate Ester Resins with Low Moisture Uptake

Abstract

Key physical characteristics including density, packing fraction, moisture uptake, and as-cured dry glass transition temperature of cyanurate networks formed from bio-based cyanate esters synthesized from the natural product anethole were examined. The results showed that both equivalently high glass transition temperatures and lower moisture uptake compared to commercial materials could be achieved, though, for the non-optimal cure schedules studied, not in the same network. The most important factor in moisture uptake appeared to be the relation between the cure schedule and the glass transition temperature of the developing network. By optimizing these parameters, it may be possible to produce networks that exhibit both a higher glass transition temperature as well as lower moisture uptake compared to commercial materials.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Aug 22, 2012
Accession Number
ADA582639

Entities

People

  • Andrew J. Guenthner
  • Christopher Sahagun
  • Joseph M Mabry
  • Josiah Reams
  • Matthew J. Davis

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Space

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Composite Materials
  • Environment
  • Glass
  • Glass Transition Temperature
  • Information Operations
  • Materials
  • Materials Science
  • Military Research
  • Moisture
  • Physical Properties
  • Resilience
  • Resins
  • Rigidity
  • Transition Temperature
  • Transitions

Readers

  • Operations Research
  • Polymer Science and Engineering.