Steam Regeneration of Adsorbents and Photocatalytic Destruction of Organic Compounds (PREPRINT)

Abstract

A treatment strategy is examined where organic compounds in aqueous phase are first removed by fixed-bed adsorption, followed by off-line regeneration of spent adsorbent and clean up of regeneration fluid by photocatalytic oxidation. The regeneration of adsorbents is conducted using saturated steam at 160 deg. C. This treatment strategy is examined with the following organic compounds; tetrachloroethylene (PCE), carbon tetrachloride (CCl4), p-dichlorobenzene (p-DCB), o-chlorobiphenly (o-PCB), and methyl ethyl ketone (MEK). For 6 cycles of adsorption and regeneration with each compound, the adsorption capacity of the adsorbent for PCE, p-DCB, CCl4 and MEK is completely recovered using the steam regeneration process. In the case of o-PCB, there is about 20% loss in adsorbent capacity after the first cycle, however, the adsorption capacity for cycles 2 through 6 is almost the same. The phototcatalytic oxidation process is observed to be effective for the destruction of desorbed organic compounds in the aqueous phase.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1994
Accession Number
ADA585363

Entities

People

  • David W. Hand
  • John C. Crittenden
  • Mike Dziobak
  • Rominder P. Suri

Organizations

  • Michigan Technological University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Air Force
  • Aromatic Compounds
  • Aromatic Hydrocarbons
  • Carbon Tetrachloride
  • Chemical Engineering
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Electron Acceptors
  • Environmental Engineering
  • Hydrocarbon Fuels
  • Organic Chemistry
  • Organic Compounds
  • Oxidation
  • Titanium
  • Titanium Dioxide
  • United States

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Aquatic Ecology