Laser-Induced Breakdown Spectroscopy: A Review of Applied Explosive Detection

Abstract

The complex chemical nature of the current military environment complicates the ability of the Warfighter to detect an explosive threat prior to detonation. The challenge is further complicated when standoff or proximal detection is needed. In this report, results from a survey of current literature and available industry data are used to provide an assessment of laser-induced breakdown spectroscopy (LIBS) phenomenology for explosives detection, as well as recognize potential gaps in knowledge. Examination of the literature reveals that there are many strengths and challenges associated with the LIBS techniques and its variants. These challenges, such as varied signal intensities due to matrix effects, are being addressed by examining the role of pulse duration, wavelength, and fluence in LIBS and by developing parallel techniques (e.g., dual-pulse LIBS) to reduce or nearly eliminate interferents. Despite advances in the LIBS research to mitigate these matrix effects, sample analysis remains arduous due to the complex emission spectra obtained. Therefore, the use of chemometrics to aid in the discrimination of hazardous material has recently been examined with some limited success. Based on the information gathered from this report, a list of recommendations for future research and/or development to increase the utility of the technique for trace standoff explosive detection is provided.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 2013
Accession Number
ADA585868

Entities

People

  • Dimitra N Stratis-Cullum
  • Ellen L. Holthoff
  • John J. Brady
  • Mikella E. Farrell
  • Paul M. Pellegrino
  • Stephen D. Roberson

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Biomedical
  • Counter IED
  • Counter WMD
  • Energy and Power Technologies
  • Sensors

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Detection
  • Energetic Materials
  • Explosives
  • Laser Applications
  • Laser Beams
  • Laser Pulses
  • Laser-Induced Breakdown Spectroscopy
  • Lasers
  • Light (Electromagnetic Radiation)
  • Light Sources
  • Liquid Chromatography
  • Optics
  • Quantum Cascade Lasers
  • Spectra
  • Spectroscopy

Fields of Study

  • Physics

Readers

  • Pulsed Power and Plasma Physics.
  • Sensor Fusion and Tracking Systems.
  • Systems Analysis and Design

Technology Areas

  • Directed Energy