Long Lived, Electronically Excited Atoms and Molecules: Excitation, Detection, Excitation Transfer and Spectroscopy

Abstract

The objective of the research project is to explore the unimolecular and collisional excitation and decay mechanisms, reactivity and detectivity of molecules in metastable triplet states. The two primary research accomplishments are: (1) formulation and testing of a new and rigorous deconvolution procedure to completely characterize the mechanism of doorway mediated inter-system crossing and (2) observation of Franck-Condon and energy resonance controlled electronic excitation transfer between Xe 3P2 metastable atoms and N2 molecules.

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Document Details

Document Type
Technical Report
Publication Date
Sep 08, 2008
Accession Number
ADA588315

Entities

People

  • Robert W. Field

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Acetylenes
  • Alkynes
  • Coordinate Systems
  • Couplings
  • Crossings
  • Detection
  • Excitation
  • High Pressure
  • Molecules
  • Observation
  • Pattern Recognition
  • Polyatomic Molecules
  • Quantum Properties
  • Resonance
  • Spectra
  • Spectroscopy
  • Spin-Orbit Interaction

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics
  • Systems Analysis and Design

Technology Areas

  • Microelectronics