(HBCU) Doped Graphene and Graphite as a Potential High Temperature Superconductor

Abstract

We have observed possible superconductivity using standard resistance vs. temperature techniques in phosphorous ion implanted Highly Oriented Pyrolytic Graphite. The onset appeared to be above 100 K and quenching by an applied magnetic field was observed. Four boron implanted samples showed no signs of becoming superconductive whereas all four initial and eight subsequent samples that were implanted with phosphorous showed at least some sign of the existence of small amounts of the possibly superconducting phases. The observed onset temperature is dependent on both the number of electron donors present and the amount of damage done to the graphene sub-layers in the Highly Oriented Pyrolytic Graphite samples. Measurements using graphene multilayers exfoliated from doped Highly Oriented Pyrolytic Graphite confirm that the effect is seen with donor dopants and not with neutral or acceptor dopants. Additionally, steps are clearly observable at temperatures that are multiples of 60K. These often extend to near room temperature.

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Document Details

Document Type
Technical Report
Publication Date
Jul 23, 2013
Accession Number
ADA588862

Entities

People

  • Grover L. Larkins Jr
  • Yuriy A Vlasov

Organizations

  • Florida International University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Abstracts
  • African Americans
  • Air Force
  • Air Force Research Laboratories
  • Data Storage Systems
  • Department Of Defense
  • Electron Donors
  • Graphene
  • Graphitic Materials
  • High Temperature
  • High Temperature Superconductors
  • Ion Implantation
  • Magnetic Fields
  • Resistance
  • Standards
  • Superconductivity
  • Superconductors

Fields of Study

  • Physics

Readers

  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Superconducting Magnet Technology
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene