The Pickup Stick Transistor

Abstract

Precise control over the electronic properties of the carbon nanotubes is key to their practical application in plastic electronics. In the present work, we have extended carbon nanotube functionalization via a 2-2 cycloaddition to electron withdrawing non-fluorinated olefins as well. Our results show that this is a fairly general approach, independent of specifics of the adderid, to converting the grown mixture of metal and semiconductor tubes into high mobility semiconducting tubes without tedious of separation requirements. Thin film transistors fabricated with functionalized tubes exhibit mobilities of 10-30 sq cm/sec and on/off ratios in excess of 10(exp 6). This simple functionalization approach represents a low cost path to high performance semiconducting inks for printable electronics.

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Document Details

Document Type
Technical Report
Publication Date
Mar 04, 2011
Accession Number
ADA590147

Entities

People

  • George G. Malliaras
  • Graciela B. Blanchet

Organizations

  • Cornell University

Tags

DTIC Thesaurus Topics

  • Alkenes
  • Band Structures
  • Carbon Nanotubes
  • Electrical Properties
  • Electronics
  • Electrons
  • Fermi Levels
  • Films
  • Fullerenes
  • Materials
  • Mobility
  • Scattering
  • Semiconductors
  • Thin Film Transistors
  • Thin Films
  • Transistors

Readers

  • Integrated Circuit Design and Technology.
  • Nanoscale Plasmonic Nanotechnology
  • Organic Chemistry

Technology Areas

  • Microelectronics