The Search for New High-Energy-Density Materials

Abstract

The objectives of this DTRA project were to design, by using first-principles density functional theory, new superhalogens capable of involving inner core electrons in chemical bonding, validate the theoretical predictions by carrying out photoelectron spectroscopy experiments, and use thus validated theory to guide experiments in focused discovery of new high energy density materials. Superhalogens belong to a class of highly electronegative species composed of a metal atom at the core surrounded by halogen or oxygen atoms and have electron affinities that are substantially larger than those of the halogen atoms.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2014
Accession Number
ADA592904

Entities

People

  • Charles Weatherford
  • Gennady L Gutsev
  • Kit H Bowen
  • Purusottam Jena

Organizations

  • Virginia Commonwealth University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemistry
  • Density Functional Theory
  • Department Of State
  • Ground State
  • Group 11 Elements
  • Halogens
  • High Energy
  • Mass Spectra
  • Materials
  • Materials Science
  • Metals
  • Photoelectron Spectra
  • Physical Chemistry
  • Spectroscopy
  • Students
  • Subatomic Particles
  • Transition Metals

Fields of Study

  • Physics

Readers

  • Quantum Chemistry
  • Systems Analysis and Design

Technology Areas

  • Microelectronics