Preparation and Characterization of High Dielectric Constant Polymer Films

Abstract

Electroactive polymers are an emerging class of actuating materials capable of generating large displacements and fast response times. Dielectric actuators operate on the principle of Maxwell stress and their response is highly dependent on the material's electrical and mechanical properties. Unfilled and composite films based on a thermoplastic polyurethane were prepared using solvent cast methods, and their dielectric properties were determined. Dielectric constants of up to 52.5 at 100 Hz were measured. The observed permittivities of the composites were consistent with the predictions of the Bruggeman model. Dielectric breakdown strength varied greatly from position to position on each film, reflecting the large statistical variation in flaw density over each film's area. For polyurethane/BaTiO3 composite films, there was no significant change in breakdown strength with increasing barium titanate concentration.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 2002
Accession Number
ADA596413

Entities

People

  • Jeff Szabo
  • Nick Harrison

Organizations

  • Defence Research and Development Canada

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Barium Titanates
  • Ceramic Materials
  • Composite Materials
  • Dielectric Permittivity
  • Dielectric Polymers
  • Dielectric Properties
  • Dielectrics
  • Equations
  • Films
  • Frequency
  • High Voltage
  • Materials
  • Mechanical Properties
  • Payload
  • Polymeric Films
  • Polymers
  • Thin Films

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Polymer Science and Technology
  • Reinforced Composite Materials