Ultraviolet Light Emitting Diode Use in Advanced Oxidation Processes

Abstract

Cleanup from a hazardous chemical release can result in large volumes of water containing hazardous materials, such as organophosphates. Unfortunately, this water cannot be treated in a municipal wastewater treatment plant without adversely affecting the performance of the plant. A known method for pretreating this water to prepare it for processing in a traditional treatment plant includes the addition of hydrogen peroxide, followed by ultraviolet (UV) light exposure to form reactive hydroxyl radicals which oxidize the chemical. Light emitting diodes (LEDs) are explored as a UV source as they are durable; compact; can be powered by low voltage, direct current from solar cells or batteries; and do not contain other hazardous materials, making them useful in a tactical environment. This research evaluated the operating mode (continuous or pulsed current) of 240 nanometer UV LEDs for application in such an advanced oxidation process. The experimental results demonstrated the production of hydroxyl radicals from hydrogen peroxide from both continuously driven and pulsed UV LEDs. However, continuously driven UV LEDs were shown to be more effective than pulsed in this application.

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Document Details

Document Type
Technical Report
Publication Date
Mar 27, 2014
Accession Number
ADA598706

Entities

People

  • Kelsey L. Duckworth

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical
  • Sensors

DTIC Thesaurus Topics

  • Advanced Oxidation Processes
  • Air Force
  • Chemical Synthesis
  • Chemistry
  • Direct Current
  • Energy Consumption
  • Environment
  • Hazardous Materials
  • Hydroxyl Radical
  • Light Emitting Diodes
  • Low Voltage
  • Materials
  • Microbiology
  • Organic Compounds
  • Rocket Oxidizers
  • Solar Cells
  • Voltage

Fields of Study

  • Materials science

Readers

  • Environmental Engineering
  • Optical Physics and Photonics.
  • Polymer Science and Engineering.