Hexachloroethane Obscurant Replacement

Abstract

A variety of pyrotechnic compositions were investigated for their viability as replacements for hexachloroethane based obscurants. The investigations included combustion modeling, ingredient and composition thermal compatibility and sensitivity to significant impact, friction and electrostatic discharge events. Candidates were screened through the combustion of small samples {less than ten grams} via open burning and combustion in a 100 cubic foot chamber to determine smoke density and analyze for toxicity of combustion gases and particulates. Compositions containing boron potassium nitrate igniter blended with halide salts {cesium, potassium and ammonium} were studied in greatest detail. Solids produced from the combustion of the specific compositions selected for study were not totally dispersed in aerosol form; significant solid slag formation was observed. Thus, smoke density efficiency was only one quarter of that of the hexachloroethane containing baseline. The addition of lower levels of the halide salt coolant to the boron potassium nitrate igniter may improve overall obscurant efficiency. Although the specific formulations tested did not perform as well as the hexachloroethane baseline, formulation variants were identified which should have improved performance.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2012
Accession Number
ADA600417

Entities

People

  • Nathan Seidner
  • Reed Blau

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical

DTIC Thesaurus Topics

  • Alkali Metals
  • Aluminum Oxides
  • Carbon Monoxide
  • Ceramic Materials
  • Chemical Elements
  • Combustion
  • Combustion Products
  • Dielectric Gases
  • Friction
  • Material Degradation Processes
  • Materials Laboratories
  • Materials Testing
  • Measurement
  • Nitrogen Oxides
  • Oxygen
  • Particle Size
  • Particles

Readers

  • Analytical Chemistry
  • Combustion science or combustion engineering.
  • Marine Mammal Biology