Tunable Friction Behavior of Oriented Carbon Nanotube Films

Abstract

Measured friction coefficients of carbon nanotubes vary widely from microns less than 0.1-microns less than 1.0, while theoretical studies suggest intrinsically high friction coefficients, approaching unity. Here we report that measured friction coefficients of MWNT films are strong functions of surface chemistry and temperature, but are not dependent on the presence of water vapor. We hypothesize that the origin of the temperature dependence arises from the interaction of the surface chemical groups on the nanotubes and rubbing counterface. The friction coefficient of individual films can be easily tuned by changing the surface temperature and chemistry of either the countersurface or the nanotubes, we have demonstrated the ability to create and control high and low friction pairs through plasma treatments of the nanotube films with argon, hydrogen, nitrogen, and oxygen. This behavior is completely reversible, and when coupled with the superior strength, thermal, and electrical properties of nanotubes, provides a versatile tunable, multifunctional tribological system.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2006
Accession Number
ADA600850

Entities

People

  • A. A. Voevodin
  • Christopher Muratore
  • G. R. Bourne
  • L. S. Schadler
  • P. L. Dickrell
  • Pulickel Ajayan
  • S. K. Pal
  • W. Gregory Sawyer

Organizations

  • University of Florida

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Carbon Nanotubes
  • Chemical Vapor Deposition
  • Chemistry
  • Electrical Properties
  • Electron Microscopy
  • Engineering
  • Environment
  • Friction
  • Fullerenes
  • Heat Of Activation
  • Hydrogen Bonds
  • Materials
  • Materials Science
  • Orientation (Direction)
  • Scanning Electron Microscopy
  • Surface Chemistry
  • Surface Temperature

Fields of Study

  • Physics

Readers

  • Nanocomposite Materials Science
  • Spectroscopy.
  • Tribology (the study of the boundary interaction between sliding surfaces, lubrication, wear and friction).