Chromophores and Materials for Temporal and Frequency Agile Non-Linear Absorption

Abstract

This research program is focused on development of organometallic chromophore systems for application in temporal and frequency agile non-linear absorption materials. The program is based on prior investigations carried out in our labs in which a new class of organometallic materials have been developed that display non-linear absorption via a dual-mode mechanism involving two-photon absorption (2PA) and excited state absorption (ESA). The work has the broad objective of developing new organometallic chromophores and materials that display very effective non-linear response to laser pulses ranging from picoseconds to nanoseconds in the visible and near-infrared spectral regimes. The project is carried out primarily at the University of Florida, in close coordination with the Agile Limiting group at the Air Force Research Laboratory/Materials and Manufacturing Directorate (AFRL/MLPJ) in order to complement their ongoing efforts which are related development of materials for non-linear optical application. Materials developed in the proposed program that exhibit promising non-linear absorption properties will be transitioned to the AFRL/MLPJ group for more extensive testing in specific optical limiting formats.

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Document Details

Document Type
Technical Report
Publication Date
May 31, 2014
Accession Number
ADA603136

Entities

People

  • Kirk Sullivan Schanze

Organizations

  • University of Florida

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Air Force
  • Air Force Research Laboratories
  • Alkenes
  • Chromophores
  • Controlled Atmospheres
  • Dual Mode
  • Efficiency
  • Emission Spectroscopy
  • Fabrication
  • Fluorescence
  • Ground State
  • Heavy Metals
  • Materials
  • Military Research
  • Spectra

Readers

  • Optical Physics and Photonics.
  • Research Science/Academic Research

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers