Room Temperature Deposition Processes Mediated By Ultrafast Photo-Excited Hot Electrons

Abstract

The goal of the DARPA Local Control of Materials Synthesis (LoCo) program is to develop a generally applicable low-temperature process for the deposition of thin films, whose current minimum processing temperature exceeds the damage threshold temperatures of substrates of interest to the DoD. Early in the program, the representative thin film material was designated to be diamond. Conventional CVD diamond deposition requires temperatures greater than ~ 700 0C, which results in severe degradation of many substrates of interest. To address this challenging scientific and technological problem, we have identified a novel approach. In this approach, wavelength specific, femtosecond laser pulses are used to control material processes, particularly growth processes, at the quantum level. Such an approach arises out of a focus on fundamental issues of non-equilibrium many-body physics that have been only recently addressed. We are pleased to report that our research team has exceeded the goals outlined for the first phase of the program and have demonstrated high-quality diamond growth at substantially lower temperatures. Our results demonstrate that this unique approach holds great promise for addressing and solving this important problem. Clearly, additional research needs to be carried out to facilitate further development and eventual implementation.

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Document Details

Document Type
Technical Report
Publication Date
Jan 30, 2014
Accession Number
ADA603598

Entities

People

  • J. L. Davidson
  • Norman Tolk
  • R. Mu
  • Weng P. Kang

Organizations

  • Vanderbilt University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Charge Carriers
  • Chemical Reactions
  • Chemical Vapor Deposition
  • Department Of Defense
  • Diamond Films
  • Electron Density
  • Electrons
  • Energy Transfer
  • Films
  • Low Temperature
  • Materials
  • Materials Science
  • Raman Spectra
  • Semiconductors
  • Students
  • Surface Reactions
  • Thin Films

Readers

  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Semiconductor Device Technology
  • Systems Analysis and Design

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene
  • Quantum Computing