Comparison of Vibrational Relaxation Modeling for Strongly Non-Equilibrium Flows

Abstract

The detailed description of the vibrational energy content is important for many gas flow processes including experimental gas measurement techniques, shock layer vibration-dissociation coupling, and vibrational energy freezing in strong expansions. Various vibrational relaxation models have been developed for use within the direct simulation Monte Carlo (DSMC) method. This study compares the Larsen-Borgnakke and Forced Harmonic Oscillator vibrational relaxation models through comparison with detailed quasi-classical trajectory (QCT) results for an atom-diatom system with focus on the effects of the form of the relaxation model. These QCT results have been extensively compared with measured data and provide a unique opportunity to evaluate these inelastic models. This work also compares the results from each model for a vibrationally exciting relaxation problem. Even when the two models have consistent vibrational collision numbers to match bulk temperature predictions for relaxation problems, the predicted evolution of the vibrational distribution function differs. This disagreement results in different prediction of radiative emission spectra.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2014
Accession Number
ADA604477

Entities

People

  • Iain D. Boyd
  • Matthew Braunstein
  • Timothy R. Deschenes

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Air Force Research Laboratories
  • Collisions
  • Computational Fluid Dynamics
  • Distribution Functions
  • Emission
  • Emission Spectra
  • Energy
  • Energy Transfer
  • Flow
  • Fluid Dynamics
  • Measurement
  • Monte Carlo Method
  • Oscillators
  • Personal Information Managers
  • Spectra
  • Trajectories
  • Vibrational Relaxation

Fields of Study

  • Physics

Readers

  • Fluid Dynamics.
  • Molecular Photonics/Laser Physics
  • Quantum Chemistry