Dislocation Etching Solutions for Mercury Cadmium Selenide

Abstract

Mercury cadmium selenide (Hg1-xCdxSe) is a possible alternative material to mercury cadmium telluride (Hg1 xCdxTe) for infrared (IR) sensor applications, but etch pit density (EPD) measurements are required to measure dislocations that affect device performance. No EPD solutions have been reported for Hg1 xCdxSe, and standard EPD solutions for Hg1 xCdxTe have proved ineffective. Thus, a new etching solution is required for EPD measurements of Hg1 xCdxSe. Samples were etched in various solutions and the resulting pits were observed using Nomarski microscopy and scanning electron microscopy (SEM). Solutions consisting of nitric and hydrochloric acid produced mainly trapezoid-shaped pits, but with flat or rounded bottoms rather than converging to a single point as expected. One solution consisting of nitric, hydrochloric, and phosphoric acid produced hexagonal pits that converged at a single point as expected, but this solution was unstable and these pits could not be repeated on any other sample. Further experiments are required to produce an etching solution that consistently forms pits that converge on a single point and then transmission electron microscopy (TEM) measurements will need to be performed to confirmed that these pits correspond to a dislocation thus enabling EPD measurement of Hg1-xCdxSe.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 2014
Accession Number
ADA609573

Entities

People

  • Kevin Doyle
  • Sudhir Trivedi

Organizations

  • Oak Ridge Associated Universities

Tags

Communities of Interest

  • Sensors

DTIC Thesaurus Topics

  • Acetic Acid
  • Acids
  • Chemistry
  • Dislocations
  • Electron Microscopy
  • Electrons
  • Hydrochloric Acid
  • Lactic Acid
  • Materials
  • Measurement
  • Microscopy
  • Military Research
  • Nitric Acid
  • Phosphoric Acids
  • Scanning Electron Microscopy
  • Standards
  • Tellurides

Fields of Study

  • Materials science

Readers

  • Geochemistry
  • Materials Science and Engineering.
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Microelectronics