Synthesis and Characterization of Hexagonal Boron Nitride (h- BN) Films

Abstract

The large-area growth of hexagonal boron nitride (h-BN) with controllable thickness (number of layers) and down to the 1-2 layers was demonstrated. In addition to the standard characterization tools used for h-BN films, such as, scanning and transmission electron microscopies (SEM and TEM), Raman spectroscopy and mapping and x-ray photoelectron spectroscopy (XPS), other less common methodologies were used as well. For example; low energy electron microscopy and diffraction was found to provide large-area and accurate number of layers; Time of flight secondary ion mass spectroscopy (TOF-SIMS) provided with a 3D mapping of elements and photoluminescence (PL) measurements were detected even from a 1-2 layers on top of a thin graphite layer, and thus, proving the presence of the h-BN phase on top of the graphene/graphite when being very challenging to do so by means of other methodologies. These results allowed us to study in better detail the growth mechanism and few manuscripts are in preparation. We believe our work will lead to a better understanding of the h-BN growth process and thus pave the way to a wide variety of applications.

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Document Details

Document Type
Technical Report
Publication Date
Jan 09, 2014
Accession Number
ADA616097

Entities

People

  • Ariel Ismach
  • Harry Chao
  • Rodney S. Ruoff
  • Sanjay Banerjee

Organizations

  • University of Texas at Austin

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Ceramic Materials
  • Chemical Vapor Deposition
  • Electron Microscopes
  • Electron Microscopy
  • Engineering
  • Graphene
  • Graphitic Materials
  • Materials
  • Materials Processing
  • Materials Science
  • Materials Testing
  • Measurement
  • Microscopes
  • Microscopy
  • Spectra
  • Spectroscopy
  • Students

Fields of Study

  • Materials science

Readers

  • Systems Analysis and Design
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene