The Effect of Malathion on the Activity and Performance of Activated Sludge

Abstract

Decontamination activities following a chemical weapons incident may generate significant quantities of contaminated wash water that may enter the wastewater collection system either intentionally or accidentally. This raises concerns about the effect of chemical warfare agents (CWAs) on the operation of a biological wastewater treatment plant. The goal of the study was to evaluate the effect of malathion on the activity and performance of activated sludge. Malathion is an organophosphate (OP) and is considered an environmental surrogate for VX. This study employed respirometry, short term batch tests, and long term exposure experiments to investigate the effects of different concentrations of malathion on bioreactor performance. Short-term exposure to malathion may depress microbial respiration, however, short-term batch tests showed that chemical oxygen demand (COD) removal was not negatively impacted by the presence of malathion concentrations of 0.1 or 3 mg/L. Unlike COD removal, ammonia-N removal was slowed by the presence of malathion at both 0.1 and 3 mg/L with a positive correlation of the removal rate to the quantity of total suspended solids. Long-term exposure experiments demonstrated that both COD removal and Nitrate production were negatively affected at concentrations of 3.0 mg/L and unaffected at concentrations of 0.1 mg/L.

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Document Details

Document Type
Technical Report
Publication Date
Mar 26, 2015
Accession Number
ADA616155

Entities

People

  • Erik G. Rauglas

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemical Weapons
  • Chemistry
  • Cyanides
  • Environmental Protection
  • Mass Spectrometry
  • Medical Personnel
  • Mustard Agents
  • Nerve Agents
  • Organic Chemistry
  • Phosgene
  • Sodium Compounds
  • Therapy
  • United States
  • Warfare

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Auditory Neuroscience/Auditory Physiology.
  • Environmental Engineering.

Technology Areas

  • Biotechnology
  • Biotechnology - Bioremediation