Water Transport in Bicontinuous, Phase-Separated Membranes Made from Reactive Block Copolymers

Abstract

Heat buildup and the effective lifespan of current chemical agent protection for military personnel are still concerns. A semipermeable membrane that allows sweat to escape a chemical protection garment, while rejecting chemical agents, would provide a potential solution for both of these issues. Few semipermeable membranes transport water vapor at a sufficient rate to cool a Soldier working at moderate levels of effort, and the mechanical properties of these materials are also of concern. Membranes fabricated from reactive block copolymers and a small molecule cross-linker using ring-opening metathesis chemistry were tested for their water transport properties. These materials were found to transport water faster than current commercially available membranes at lower humidity levels. The mechanical properties of the membrane still limit its use as a garment in chemical agent protection.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 2014
Accession Number
ADA616420

Entities

People

  • Frederick L Beyer
  • Natalie L Pomerantz
  • Samuel C. Price
  • Walter X. Zukas

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Human Systems

DTIC Thesaurus Topics

  • Alcohols
  • Block Copolymers
  • Copolymers
  • Detectors
  • Dielectric Gases
  • Films
  • Flow
  • Humidity
  • Hypervelocity Flow
  • Low Humidity
  • Magnetic Resonance
  • Materials
  • Mechanical Properties
  • Polymers
  • Transport Ships
  • Vapors
  • Water Vapor

Readers

  • Exercise and Sports Science.
  • Polymer Science and Technology
  • Underwater engineering and Marine Technology.

Technology Areas

  • Microelectronics