The Effect of Soil Properties on Metal Bioavailability: Field Scale Validation to Support Regulatory Acceptance

Abstract

The U.S. Department of Defense (DoD) faces a potentially daunting task of remediating thousands of metal-contaminated sites within the U.S. and its territories that contain unacceptable levels of the toxic metal(loid)s arsenic (As), cadmium (Cd), chromium (Cr), and lead (Pb). With the exception of Pb contaminated soils, human health and ecological risk drivers have prompted the U.S. Environmental Protection Agency (EPA) to assume that the total soil metal concentration is 100% bioavailable. Previous Strategic Environmental Research and Development Program (SERDP) funded research (ER-1166) has shown that the ubiquitous metal-sequestering properties of soil can significantly lower the bioavailability and risk of heavy metals to human and ecological receptors. This investigation brought together regulators, EPA, end-users, and scientists to demonstrate the applicability of these concepts by showing that simple, readily available soil properties can often be used to predict the bioavailability of As, Cd, Cr, and Pb with a reasonable level of confidence. We have shown that in vitro methods can often be used for risk assessment of toxic metals in soil by comparing in vitro and in vivo metal bioavailability studies.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 2014
Accession Number
ADA618065

Entities

Organizations

  • Environmental Security Technology Certification Program

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Arsenates
  • Chemical Analysis
  • Chemical Properties
  • Chemical Speciation
  • Chemical Synthesis
  • Chemistry
  • Detectors
  • Digestive System Processes
  • Ecology
  • Ecotoxicology
  • Environment
  • Environmental Pollutants
  • Environmental Protection
  • Physical Properties
  • Scattering
  • Spectra
  • Toxicity

Fields of Study

  • Environmental science

Readers

  • Agricultural Chemistry/Soil Science
  • Systems Analysis and Design