Demonstration of the B4C/NaIO4/PTFE Delay in the U.S. Army Hand-Held Signal

Abstract

A pyrotechnic time delay based on boron carbide has been demonstrated as a viable replacement for the perchlorate- and chromate-containing formulation currently used in U.S. Army hand-held signals. Tests involving fully assembled hand-held signal rockets were conducted to evaluate the characteristics of the B4C/NaIO4/PTFE delay system in an operational configuration. The delay times observed in such dynamic tests were substantially shorter than those expected from prior static testing, necessitating the use of very slowburning compositions to achieve the desired 5-6 s dynamic delay time. The behavior of the system at extreme temperatures (-54 and +71 deg. C) was also evaluated, confirming its reliability and safety. Impact, friction, and electrostatic discharge tests have shown that the boron carbide-based delay is insensitive to unintended ignition. TGA/DSC analysis indicated an ignition temperature of 475 deg. C, well above the decomposition temperature of NaIO4 and above the melting points of NaIO3 and PTFE.

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Document Details

Document Type
Technical Report
Publication Date
May 20, 2015
Accession Number
ADA618074

Entities

People

  • Anthony P. Shaw
  • Henry A. Grau Jr.
  • Jay C. Poret
  • Robert A. Gilbert Jr.

Organizations

  • United States Army Armament Research, Development and Engineering Center

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Boron Carbides
  • Burning Rate
  • Chemical Synthesis
  • Chemistry
  • Chromium Compounds
  • Combustion
  • Decomposition
  • Dynamic Tests
  • Elements
  • Energetic Materials
  • Fluoropolymers
  • Heat Transfer
  • Ignition
  • Materials
  • Static Tests
  • Thyroid Therapy Drugs

Readers

  • Rocket Propulsion.