Surface Impact Simulations of Helium Nanodroplets

Abstract

We summarize here progress made on a two-pronged program of research, supported by AFRL, that uses theoretical and computational methods to investigate both (1) the formation of small metal atom aggregates inside the nanodroplets and (2) the desolvation and isolation of these aggregates through gentle surface impacts, or "soft landings". The first effort developed a highly parallel code suite, QDROP, that simulates the structure of neat and atom-doped He droplets using variational path integral (VPI) quantum Monte Carlo methods. We have used QDROP to study He droplets with as many as N = 1000 atoms of aluminum and magnesium doped systems. The second effort developed a framework for modeling droplet-surface impacts using a "dressed classical dynamics" code for simulating the real-time dynamics. These simulations are a modified version of zero-point averaged dynamics, which captures atomic delocalization of the helium atoms characteristic of the quantum solvent, but allow the single-particle wavefunctions to vary throughout the simulation, thereby allowing the densities to redistribute to their local environment.

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Document Details

Document Type
Technical Report
Publication Date
Jun 30, 2015
Accession Number
ADA622739

Entities

People

  • Robert J. Hinde

Organizations

  • University of Tennessee system

Tags

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Computational Science
  • Crystal Lattices
  • Density Functional Theory
  • Dynamics
  • Energetic Materials
  • Energy
  • Energy Transfer
  • Metals
  • Molecular Dynamics
  • Monte Carlo Method
  • Particles
  • Path Integrals
  • Probability Distributions
  • Simulations
  • Soft Landings

Fields of Study

  • Physics

Readers

  • Computational Fluid Dynamics (CFD)
  • Quantum Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Quantum Computing