Structure-Property Relationships for Polycyanurate Networks Derived from Renewable Sources (Briefing Charts)

Abstract

The recent synthesis of a wide variety of cyanate ester monomers that may be derived from renewable resources has created a newly available set of chemical structures that, due to a wide range of chemical features, provide a unique opportunity for the development of quantitative structure-property relationships for dicyanate esters and their polymerized networks. Specific structure-property relationships for monomer melting point, glass transition temperature at full conversion, and char yields at 600 C under nitrogen and air have been developed with the aid of partial least squares methods. The predictions inherent in these structure-property relationships are examined and compared to predictions based on ordinary least squares methods. Specific predictions for the properties of two as-yet unsynthesized dicyanate ester monomers derived from renewable resources are also presented.

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Document Details

Document Type
Technical Report
Publication Date
Aug 18, 2015
Accession Number
ADA627452

Entities

People

  • Andrew J. Guenthner
  • Joseph M Mabry
  • Michael D. Ford

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Air Force
  • Air Force Research Laboratories
  • Data Sets
  • Department Of Defense
  • Glass Transition Temperature
  • Information Operations
  • Least Squares Method
  • Materials
  • Melting
  • Melting Point
  • Military Research
  • Physical Properties
  • Spine
  • Test Sets
  • Transition Temperature
  • Validation

Fields of Study

  • Chemistry

Readers

  • Computational Modeling and Simulation
  • Polymer Science and Engineering.