Microbial Community and Environmental Factors Affecting Copper Complexation in a Navy Harbor

Abstract

LONG-TERM GOAL. Our long term goal is to understand the interactions between microorganisms and trace metals in estuaries that are heavily utilized by Naval operations. We are particularly interested in the production of high-affinity, copper-complexing ligands by microbial populations in response to elevated copper concentrations. OBJECTIVES. Strong, dissolved, copper-complexing ligands are known to control copper speciation and bioavailability in most marine waters. We are testing the hypothesis that metal-responsive production of such ligands occurs in the Elizabeth River estuary, and that picoplankton and bacterioplankton produce the ligands. Recent studies utilizing cultures of marine picoplankton (Synechococcus) and bacterioplankton (Vibrio) have demonstrated that, when the cultures are exposed to elevated copper concentrations, these microbes produce copper-complexing ligands having copper-binding strengths similar to those found in marine waters. The primary objective of our study is to extend these observations to field conditions and natural assemblages of estuarine microorganisms in a Navy harbor. An additional objective is isolation and further characterization of the strong, coppercomplexing ligands produced by microbes.

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Document Details

Document Type
Technical Report
Publication Date
Sep 30, 1999
Accession Number
ADA629716

Entities

People

  • Andrew S. Gordon
  • John R. Donat

Organizations

  • Old Dominion University

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Azides
  • Bacteria
  • Biochemistry
  • Biological Sciences
  • Chemical Speciation
  • Chemistry
  • Communities
  • Cyanobacteria
  • Field Conditions
  • Incubation
  • Metals
  • Microbiology
  • Microorganisms
  • Naval Operations
  • Navy
  • Sodium Azides
  • Sodium Compounds

Fields of Study

  • Environmental science

Readers

  • Environmental Engineering
  • Marine Ecotoxicology
  • Molecular and Cellular Biochemistry

Technology Areas

  • Biotechnology
  • Biotechnology - Bioremediation