Personal Cooling Fabric Based on Polymeric Thermoelectrics

Abstract

This report documents a 3-year effort (completed in 2012) sponsored by the Defense Threat Reduction Agency (DTRA) to develop novel polymeric thermoelectric (TE) materials, to develop an understanding of the TE behavior of these materials, and to provide materials from which a personal cooling fabric could be developed. Organic polymers offer a light weight, environmentally friendly, and low cost alternative to the widely used inorganic TE materials. Because of their potential for good electrical conductivity and the discrete nature of their conjugated blocks, a series of poly(phenylenevinylene) (PPV) copolymers was chosen for this work. The TE Figure of Merit for films of these copolymers was found to vary over a wide range. The most promising results were obtained by blending single wall carbon nanotubes into the polymers to increase electrical conductivity. The highest value obtained for the Figure of Merit was approximately 0.01, among the highest observed for any organic thermoelectric materials. Further materials development can be expected to yield second generation TE polymers with improved properties.

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Document Details

Document Type
Technical Report
Publication Date
Jul 28, 2016
Accession Number
ADA637309

Entities

People

  • Eugene Wilusz
  • Frank E Karasz
  • Ljiljana Korugic-karasz
  • Patrick S. Taylor
  • Paul M Lahti

Organizations

  • United States Army Soldier Systems Center

Tags

Communities of Interest

  • Energy and Power Technologies
  • Human Systems

DTIC Thesaurus Topics

  • Carbon Nanotubes
  • Chemical Synthesis
  • Chemistry
  • Conductive Polymers
  • Conductivity
  • Electrical Conductivity
  • Electrons
  • Environment
  • Figure Of Merit
  • Films
  • Materials
  • Materials Science
  • Molecules
  • Organic Materials
  • Peltier Effect
  • Polymeric Films
  • Polymers

Fields of Study

  • Materials science

Readers

  • Critical Infrastructure Protection in CBRN and WMD Threats.
  • Nanocomposite Materials Science
  • Polymer Science and Technology

Technology Areas

  • Microelectronics