Crosslinking Systems for Aromatic Heterocyclic Polymers

Abstract

The research described in this report is directed toward the development of a universal crosslinking agent for aromatic and aromatic heterocyclic polymers. The syntheses of materials capable of forming reactive intemediates at elevated temperature are discussed. Initial experiments on the crosslinking capabilities of several crosslinking agents are discussed. Investigation into the use of peroxides as crosslinking additives involves the synthesis of high molecular weight peroxides. Four peroxides of varying molecular weights and aromatic character have been synthesized. The effectiveness of these additives has been tested on a variety of aromatic polymers. The crosslinking effectiveness of a high molecular weight carbene precursor, 4,4'-Bis(alpha-diazobenzyl)diphenyl ether, has been tested with both model compounds and aromatic polymers.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1975
Accession Number
ADB007186

Entities

People

  • J. K. Stille
  • James F. Wolfe
  • Kaoru Iwata
  • Steven Q. Norris

Organizations

  • University of Iowa

Tags

Communities of Interest

  • C4I

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Air Force
  • Chemical Synthesis
  • Chemistry
  • Dermatologic Agents
  • Films
  • Hydrazines
  • Materials
  • Materials Laboratories
  • Mechanical Properties
  • Molecular Weight
  • Peroxides
  • Physical Properties
  • Polymeric Films
  • Polymers
  • Test And Evaluation

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology