Bridged Bicyclic Systems as Acetylcholinesterase Reactivators and Pretreatment Drugs.

Abstract

During the past year a large number substituted carbamates, thiocarbamates of various bridged aza bicyclic oximes and their methiodides and meth chlorides have been synthesized. Among these are: (i) O-(N-Substituted carbamoyl)-3-tropinone oxime methiodides and methchlorides, (ii) 0-(N-Substituted carbamoyl)-6-cyano trop-3-ene-2-one oxime methiodides, (iii) O-N-(2',3',4',6'-Tetra-0-acetyl-b-D-glucopyranosyl thiocarbamoyl)-3-tropinone oxime and its methiodide. Synthesis of 1,6-bis-N',N'-dimethyl-3'-oximino-0-carbamoyl tropanonium-N-y1 hexane diiodide and 2,5- bis-(N'N'-dimethyl-3'-oximino-0-carbamoyl tropanonium-N-yl)-toluene diiodide have been achieved. From phencyclidine a series 4-phenyl-4-0-(N-substituted carbamoyl)-4'-piperidone oxime-1'-yl-1-methyl piperidone methiodides have been synthesized. Syntheses of 0-N-substituted carbamoyl)-3-exo-dimethyl aminomethyl2-norbornone oximes and their methiodides have been accomplished.

Document Details

Document Type
Technical Report
Publication Date
Mar 30, 1990
Accession Number
ADB150776

Entities

People

  • Robert M. Moriarty

Organizations

  • University of Illinois at Chicago

Tags

DTIC Thesaurus Topics

  • Acetylcholinesterases
  • Biomolecules
  • Carbamates
  • Chemical Compounds
  • Chlorides
  • Chlorine Compounds
  • Enzymes
  • Enzymes And Coenzymes
  • Sulfur Compounds

Fields of Study

  • Chemistry

Readers

  • Neurotoxicology
  • Organic Chemistry