Energetic Polynitro Formal Plasticizers.

Abstract

Plasticizers which are commonly used in gun propellants and other energetic compositions are nitroglycerin (NG), butanetriol trinitrate (BTTN), metriol trinitrate (METN), diethylene glycol dinitrate (DEGN), and bis (2,2-dinitropropyl) formal/acetal (BDNPF/A). Disadvantages which these materials exhibit are low thermal stability due to the presence of secondary hydroxy groups (NG, BTTN), low energy (BDNPF/A, METN, DEGN), and high vapor pressure (DEGN, NG). Summary of the Invention: Accordingly, an object of this invention is to provide a new energetic plasticizer. Another object of this invention is to provide an improved energetic plasticizer having a low vapor pressure. A further object of this invention is to provide an improved plasticizer having a low melting point. Yet another object of this invention is to provide an improved plasticizer which has good thermal stability. These and other objects of this invention are accomplished by providing energetic plasticizers which are binary and ternary mixtures of bis(2,2-dinitropropyl) formal (BDNPF), bis (2,2,2-trinitroethyl) formal (TEFO), and 2,2-dinitropropyl 2,2,2-trinitroethyl formal (TNEPF).

Document Details

Document Type
Technical Report
Publication Date
Apr 27, 1987
Accession Number
ADD012819

Entities

People

  • Horst D. Adolph
  • Kyung E. Kim

Organizations

  • United States Department of the Navy

Tags

DTIC Thesaurus Topics

  • Gun Propellants
  • Inventions
  • Liquid Explosives
  • Materials
  • Melting Point
  • Nitroglycerin
  • Plasticizers
  • Polyethylene Glycols
  • Propellants
  • Thermal Stability
  • Vapor Pressure

Readers

  • Electrical Engineering
  • Organic Chemistry
  • Polymer Science and Engineering.