Improved Alkaline Earth-Oxyhalide Electrochemical Cell for Low Temperature Use.

Abstract

This invention relates in general to an alkaline earth-oxyhalide electrochemical cell and in particular, to an improved alkaline earth oxyhalide electrochemical cell for low temperature use. A typical cell includes a calcium anode, 1M Ca(AlCl4)2 thionyl chloride/75 percent Shawinigan - 25 percent acetone washed Black Pearls 2000 carbon black cathode. The improvement to this cell involves the addition of 10 volume percent bromine to the electrolyte. During discharge at about -30 C, cathode potential is raised by about 0.5 volt providing a cell voltage well above the 2.0 volt minimum which is a standard military specification. Without bromine, cell capacity is about one minute. With the addition of bromine, load voltage is initially 2.5 volts, then slowly decreases to 2.0 volts over about twelve minutes.

Document Details

Document Type
Technical Report
Publication Date
May 20, 1988
Accession Number
ADD013756

Entities

People

  • Charles W. Walker Jr.
  • Michael Binder

Organizations

  • United States Army

Tags

DTIC Thesaurus Topics

  • Cells
  • Chemical Compounds
  • Chlorides
  • Electrochemical Cells
  • Electrolytes
  • Inventions
  • Low Temperature
  • Oxyhalides
  • Specifications
  • Standards

Readers

  • Battery Technology and Engineering
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Mathematics or Statistics