Double Network Elastomers and Method of Making Same.

Abstract

A process for modifying elastomeric structures to improve mechanical properties involves subjecting a pre-cured shape of elastomeric material to an orientation technique to result in an oriented elastomeric material; and curing the oriented elastomeric material while maintaining the orientation of the elastomeric material under conditions effective to result in an elastomeric structure having a predetermined cross-link density and enhanced modulus, the magnitude of orientation being sufficient to result in the enhanced modulus. Typically, the orientation techniques used may include uniaxial extension, biaxial extension, simple shear, planar shear, and inflation. The elastomeric material be capable of strain induced crystallization or incapable of strain induced crystallization. The enhanced modulus is obtained while at least maintaining failure performance of the elastomeric structure, and the conditions during the curing are sufficient to maintain a constant cross-link density in the double network elastomer while the modulus is enhanced.

Document Details

Document Type
Technical Report
Publication Date
Mar 29, 1994
Accession Number
ADD016323

Entities

People

  • C. Michael Roland
  • P. G. Santangelo

Organizations

  • United States Department of the Navy

Tags

DTIC Thesaurus Topics

  • Amorphous Materials
  • Biomedical And Dental Materials
  • Crystallization
  • Elastomers
  • Films
  • Materials
  • Mechanical Properties
  • Orientation (Direction)
  • Polymeric Films
  • Specialty Uses Of Chemicals

Readers

  • Materials Science (Mechanical Engineering).
  • Polymer Science and Technology
  • Reinforced Composite Materials