Sidewall Passivation by Oxidation During Refractory-Metal Plasma Etching.

Abstract

Sidewalls in a pattern of a refractory metal on a substrate are passivated during plasma etching by introducing water vapor into the etching chamber. This process obtains nearly vertical sidewalls. In one exemplified embodiment, a pattern of tungsten on a chromium etch step layer was reactive ion etched. In that embodiment, the reactive ion etching was intermittently paused. After each pause, the workpiece was warmed from below about 2O%C to about room temperature. Then, water vapor was introduced into the etching chamber housing the workpiece. After the water vapor was introduced, the workpiece was cooled to below about 200C and reactive ion etching was resumed. Alternatively, water vapor can be introduced into the etching chamber continuously during plasma etching. (AN)

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Document Details

Document Type
Technical Report
Publication Date
Apr 14, 1995
Accession Number
ADD017642

Entities

People

  • Christie R. Marrian
  • John Kosakowski
  • Kelly W. Foster
  • Martin C. Peckerar
  • William Chu

Organizations

  • United States Department of the Navy

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemistry
  • Detection
  • Films
  • Flowmeters
  • Lithography
  • Materials
  • Materials Science
  • Metals
  • Patent Applications
  • Reactive Ion Etching
  • Refractory Metals
  • Substrates
  • Tungsten
  • Vapors
  • Water Vapor
  • X Ray Lithography
  • X Rays

Fields of Study

  • Materials science

Readers

  • Electrical Engineering
  • Surface Engineering/Surface Coating Technology.
  • Thin Film Deposition Science.