High Strain Piezo-Polymer

Abstract

The present invention is a new class of terpolymers for use as high strain electrostrictive polymer films. More particularly, the invention is a class of electrostrictive terpolymers comprising vinylidene fluoride (vDF), trifluoroethylene (TrFE) and at least one monomer having at least one halogen atom side group. The monomer is preferably an ethylene-based monomer and preferably selected to favor gauche- type linkage along the polymer backbone. The halogen atom side group is preferably large enough to move or cause adjacent polymer chains to be farther apart from or away from each other than in the absence of such side group, but not so large that it would inhibi% polymer crystallites from forming. The monomer is preferably a chloro-monomer such as chlorofluoroethylene (CFE). The chiorofluoroethylene (CFE) is preferably l-chloro-2- fluoroethylene or l-chloro-l-fluoroethylene. The chlorofluoroethylene (CFE) favors gauche-type linkage which favors high electrostrictive strains.

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Document Details

Document Type
Technical Report
Publication Date
Nov 21, 2003
Accession Number
ADD020142

Entities

People

  • Thomas Ramotowski

Organizations

  • United States Department of the Navy

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Sensors

DTIC Thesaurus Topics

  • Alkenes
  • Copolymers
  • Crystal Lattices
  • Crystallites
  • Crystals
  • Electric Fields
  • Electron Irradiation
  • Films
  • Fluorides
  • Halogens
  • Inventions
  • Materials
  • Molecular Dynamics
  • Polymeric Films
  • Polymers
  • Undersea Warfare
  • United States

Readers

  • Materials Science and Engineering.
  • Polymer Science and Technology