Rotational Nonequilibrium Influences in CW HF/DF Chemical Lasers,

Abstract

A theory is presented which considers either rotational equilibrium or nonequilibrium rate processes in continuous wave (CW) hydrogen fluoride (HF) or deuterium fluoride (DF) lasers. The theory is used to predict zero power gain and power spectral distributions and comparisons are made with experimental observations. The DF reaction kinetics model was found to give predictions of zero power gain which were closely correlated with experimental data. However, the HF reaction kinetics were found to produce radically different zero power gains than experimentally observed. Modifications to the reaction rages of certain vibrational-translational and vibrational-vibrational energy exchange processes were found to remove the discrepancy between the measured and predicted zero power gains. The rotational nonequilibrium theory was used to predict the power spectral distributions for HF and DF lasers and results were found to be consistent with experimental data.

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1981
Accession Number
ADP000268

Entities

People

  • J. W. Raymonda
  • L. H. Sentman
  • M. Subbiah
  • S. W. Zelazny
  • W. L. Rushmore

Organizations

  • Bell Aircraft Corporation

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Kinetics
  • Chemical Lasers
  • Continuous Waves
  • Deuterium
  • Deuterium Fluoride Lasers
  • Energy Transfer
  • Experimental Data
  • Fluorides
  • Gain
  • Hydrogen
  • Kinetics
  • Lasers
  • Power Gain
  • Shock Tubes

Fields of Study

  • Engineering
  • Physics

Readers

  • Combustion science or combustion engineering.
  • Optical Physics and Photonics.
  • Spectroscopy.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers