Methods for Detecting Moisture Degradation in Graphite-Epoxy Composites,

Abstract

Hydrothermal treatment (combined high moisture and temperature) of graphite fiber reinforced epoxy matrix composite produces irreversible deterioration in shear strength and modifies the Weibull distribution of survival probability(s). Analysis of water diffusion kinetics shows that strength degradation is dominated by the matrix bulk properties. Ultrasonic 2.25 MHz velocity transverse to the fiber axis is sensitive to current moisture content while acoustic attenuation correlates with prior moisture history and strength degradation. The high glass transition temperature of the epoxy relative to maximum moisture exposure temperature restricts extensive degradation matrix and interface. Ultrasonic methods are applied for scanning the effects of positionally variable moisture content and hydrothermal damage in a composite bar. A number of NDE methods including dynamic mechanical spectroscopy (1.0-100 Hz), NMR pulse relaxation spectroscopy, and microwave spectroscopy (2.64 GHz) are shown to provide highly resolved moisture effects data. The development of composite durability characterization and ultrasonics scanning coupled with direct measurement of bulk moisture content appears to offer a versatile NDE methodology for quantitative detection of hydrothermal aging effects on large composite structures.

Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1976
Accession Number
ADP003012

Entities

People

  • D. H. Kaelble
  • P. J. Dynes

Tags

DTIC Thesaurus Topics

  • Acoustic Attenuation
  • Aging (Materials)
  • Composite Materials
  • Composite Structures
  • Degradation
  • Epoxy Composites
  • Glass Transition Temperature
  • Graphite Epoxy Composites
  • Graphitic Materials
  • Hydrothermal Aging
  • Material Degradation Processes
  • Microwave Spectroscopy
  • Moisture
  • Moisture Content
  • Shear Strength
  • Spectroscopy
  • Transition Temperature

Readers

  • Reinforced Composite Materials
  • Thermal Physics or Thermal Science.