Measurement of High Frequency Electro-Optic Coefficient in Ferroelectric Liquid Crystal Materials,

Abstract

Ferroelectric liquid crystals (FLC's) form the thermodynamically stable Smectic C* liquid crystalline phase that is non-centrosymmetric and has macroscopic polar order. The symmetry (C sub 2) implies that FLC materials can exhibit second order nonlinear properties such as the linear electro-optic(EO) effect and second harmonic generation (SHG). In most FLC's designed for optical modulation applications these nonlinearities are small, but in principle could be made large by specifically synthesizing liquid crystal molecules which self-assemble in such a way that functional groups with large microscopic hyperpolarizabilities, Beta's, are oriented along the polar axis. By adopting this approach to produce second order nonlinear material, the problems associated with processing organic single crystals are avoided. Furthermore, the flexibility of the liquid crystal technology can be used to design materials with specific refractive indices for phase matching purposes and waveguide design. Waveguides in this material system are particularly interesting as they allow a significant increase in optical propagation length with high electric field generation capability; both important attributes for nonlinear optical phenomena. Preliminary work has already been carried out on waveguide structures whose possibilities are numerous owing to the ability to successfully align FLC's on many different substrates (including Si).

Document Details

Document Type
Technical Report
Publication Date
May 22, 1992
Accession Number
ADP007586

Entities

People

  • D. Doroski
  • Jann‐Yenq Liu
  • K. M. Johnson
  • M. G. Robinson

Organizations

  • University of Colorado Boulder

Tags

DTIC Thesaurus Topics

  • Advanced Materials
  • Crystals
  • Demographic Cohorts
  • Electric Fields
  • Engineered Materials
  • Frequency
  • Liquid Crystals
  • Materials
  • Optical Phenomena
  • Refractive Index
  • Second Harmonic Generation
  • Single Crystals
  • United Kingdom
  • Wave Phenomena
  • Waveguides

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Optical Physics and Photonics.