Design and Synthesis of Conformationally Restricted Renin Inhibitors,

Abstract

Constrained cyclic peptides have shown to be useful probes in the exploration of the conformational features of the peptide necessary for binding. In designing conformationally restricted analogs of peptides that exist in the extended conformation and contain two hydrophobic side chains on the same side, a constraint that covalently links these side chains with a hydrophobic spacer offers the advantage of maintaining hydrogen bonds between the backbone of the inhibitor and the enzyme while maximizing the hydrophobic interactions of the side chains and the binding properties of the individual side chains.

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1992
Accession Number
ADP008547

Entities

People

  • C. E. Brotherton-pleiss
  • L. D. Waterbury
  • M. S. Schwartzberg
  • S. R. Newman

Tags

DTIC Thesaurus Topics

  • Chemistry
  • Hydrogen
  • Hydrogen Bonds
  • Hydrophobic Properties
  • Inhibitors
  • Massachusetts
  • Physical Properties
  • Spine

Fields of Study

  • Chemistry

Readers

  • Molecular and Cellular Biochemistry