Development and Optimization of a Comprehensive Kinetic Model of Hydrocarbon Fuel Combustion

Abstract

The objective of the present research program is to develop a comprehensive, predictive, and detailed kinetic model of hydrocarbon combustion for aeropropulsion simulations. During the reporting period progress has been made in the following projects: (1) a comparative study of the influence of reaction rate constant and binary diffusion coefficient on laminar flame speed predictions and close coupled scattering calculations for the binary diffusion coefficients of H-He and H-Ar, (2) a study on the mechanisms for the initiation of radical chain reactions during homogeneous oxidation of unsaturated hydrocarbons, and (3) development of a comprehensive mechanism for C1-C4 fuel combustion. These three projects represent the two key ingredients that are necessary to the success of the overall research program. These are, (1) the formulation of physico-chemical properties that are relevant to kinetic model development and validation, and (2) further development of a unified and optimized kinetic model for higher hydrocarbon combustion.

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Document Details

Document Type
Technical Report
Publication Date
Jun 19, 2001
Accession Number
ADP012131

Entities

People

  • Hai Wang

Organizations

  • University of Delaware

Tags

Communities of Interest

  • C4I

DTIC Thesaurus Topics

  • Alkenes
  • Alkynes
  • Butadienes
  • Chain Reactions
  • Chemical Kinetics
  • Chemical Properties
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Computational Science
  • Decomposition
  • Diffusion Coefficient
  • Hydrocarbon Fuels
  • Hydrocarbons
  • Unsaturated Hydrocarbons

Readers

  • Combustion science or combustion engineering.
  • Computational Modeling and Simulation
  • Organic Chemistry