Hybrid High-Temperature Nanostructured Magnets
Abstract
The hysteretic behavior of two-phase permanent magnets for high-temperature applications is examined. A variety of systems have been synthesized and investigated, including Sm-Co-Cu-Ti bulk magnets. SmCo5:Cu-Ti thin-film materials, and mechanically milled Sm-Co-Zr magnets. The hybrid character of the material leads to very high room-temperature coercivities, between 30.2 and 43.6 kOe, and to the survival of a comparatively large part of the coercivity at high temperatures (12.3 kOe at 500 deg C for SmCo(6.5)Cu(0.8)Ti(0.)3). The coercivity reflects the structure and chemical composition of the material. When ferromagnetic grains are separated by a ferromagnetic boundary phase, the boundary phase acts as a pinning center, but when the grain-boundary phase has a comparatively low Curie temperature, the high-temperature magnetism of the system is that of a weakly interacting ensemble of magnetic particles. In spite of some residual paramagnetic exchange coupling, which is discussed in this work, this mechanism enhances the coercivity.
Document Details
- Document Type
- Technical Report
- Publication Date
- Apr 01, 2001
- Accession Number
- ADP012306
Entities
People
- David J. Sellmyer
- Hao Tang
- Jiawei Zhou
- R. Skomski
Organizations
- University of Nebraska–Lincoln