Development of AIIBVI Semiconductors Doped with Cr for IR Laser Application

Abstract

Electrical and optical measurements obtained with CdSe single crystals doped with chromium from a gas source CrSe over a wide temperature range (500 - 1050 deg C) are compared with ZnSe annealed in liquid metal (Zn). These processes are intended to control the concentrations of the impurity and intrinsic defects. The low temperature annealing of CdSe crystals in CrSe atmosphere allows obtaining high electron mobility up to 9000 sq cm/Vs at 80 K and demonstrates the low native defect concentration. A high temperature annealing gives rise to increased electron concentration with decreased mobility. Optical absorption measurements show that at the high annealing temperature effective doping with Cr takes place. The impurity absorption beyond the absorption edge is interpreted by the excitation of Cr(++) and Cr(+) deep levels.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2002
Accession Number
ADP012664

Entities

People

  • R. Z. Shneck
  • S. R. Rotman
  • V. A. Kasiyan
  • Z. Dashevsky

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Absorption
  • Absorption Coefficients
  • Annealing
  • Coefficients
  • Electron Mobility
  • Electrons
  • Energy Bands
  • Free Electrons
  • Heat Treatment
  • High Temperature
  • Laser Applications
  • Lasers
  • Materials
  • Optical Properties
  • Scattering
  • Semiconductors
  • Single Crystals

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics