Thermal Anneal Effects on Carbon-Hydrogen LVMs in A1GaN
Abstract
Thermal annealing effects on carbon-hydrogen (C-H) complexes defects in AlGaN grown on sapphire by metalorganic chemical vapor deposition (MOCVD) technique have been investigated using Fourier transform infrared spectroscopy (FTIR). The CH complexes in AlGaN, formed either during growth or by proton irradiation, exhibit five local vibrational modes (LVMs) due to the symmetric and asymmetric vibrational stretching modes of C-H in CH(sub n) (n = 1-3) defect complexes. It was found that the annealing temperature (T(sub a)) of 500 deg C is sufficient enough to dissociate most of the C-H complexes in AlGaN samples. A turning point annealing temperature is found around 300 deg C for un-irradiated Mg-doped sample, below which the total integrated area of the C-H LVMs continued to increase with increasing annealing temperature and reach the maximum value around 300 deg C. At T(sub a) > 300 deg C, the total integrated area of the C-H LVMs starts to decrease and the C-H complexes seem to be completely depleted at T(sub a) > 600 deg C. The depleted C-H LVMs were observed to partially recover after thermal annealing at T(sub a) > 500 deg C and waiting for aging periods of several days. This recovery behavior is explained in terms of the hydrogen being remained inside the crystal after the dissociation of C-H complexes, subsequent diffusion and recombining again with carbon atom to reform C-H complexes.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 2002
- Accession Number
- ADP012667
Entities
People
- B. D. Weaver
- M. O. Manasreh
Organizations
- University of New Mexico