Molecularly Imprinted Polymers Used as Optical Waveguides for the Detection of Fluorescent Analytes

Abstract

This article demonstrates the novel approach of fabricating molecularly imprinted polymers (MIPs) as fiber optic waveguides for the detection of fluorescent analytes. Combining a polyurethane system and the soft lithography technique of micromolding in capillaries (MIMIC), polymer waveguides of 50 micrometers and 100 micrometers dimensions were patterned onto a silicon substrate. Laser coupling into small waveguide segments has been verified visually. Binding experiments using the waveguides are currently being explored. Some preliminary binding studies have been performed, however, for smaller, freestanding filaments of sizes consistent with conventionally prepared MIP particles. Using fluorimetry measurements, templated fibers of 20 micrometers dimension preferentially bound the analyte molecules by a factor of 1.5 as compared to control polymers.

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Document Details

Document Type
Technical Report
Publication Date
Apr 05, 2002
Accession Number
ADP013610

Entities

People

  • Jennifer J. Brazier
  • Mingdi Yan
  • Scott Prahl
  • Yin-chu Chen

Organizations

  • Portland State University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Detectors
  • Fabrication
  • Films
  • Lithography
  • Materials
  • Molecules
  • Optical Waveguides
  • Photolithography
  • Polymers
  • Polyurethanes
  • Refractive Index
  • Soft Lithography
  • Surface Acoustic Waves
  • Thin Films
  • Waveguides

Fields of Study

  • Physics

Readers

  • Integrated Circuit Design and Technology.
  • Nanoscale Plasmonic Nanotechnology
  • Optical Fiber Sensing and Electromagnetic Propagation.

Technology Areas

  • Directed Energy