Synthesis of Novel Vanadium Oxide Nanotubes and Nanofibers
Abstract
We are exploring the synthesis and properties of structured vanadium oxides mainly nanotubes and nanorods. Nanotubes initially formed with surfactant templates have been readily exchanged with simple cations without change of the basal-plane structure. These compounds contain delta-like vanadium oxide layers with the vanadium in VO6 octahedra. This structure is particularly suitable for redox reactions. In this paper we report on synthesis of vanadium oxide (NH4)(x)V2O(5-delta)(dot)nH2O rods using organic polymer as template. This compound has been synthesized by sol-gel reaction and subsequent hydrothermal treatment. TGA, SEM, XRD and FTIR were used to characterize this compound. Thermal analysis of this compound shows that the fibrous morphology is maintained when it is heated in nitrogen and oxygen above 300 deg. C. However, in both cases the size of the fibers decreases. Performance of this compound as cathode material in secondary electrolyte has been investigated using LiPF6 as electrolyte. A capacity of 140 mAh/g was obtained which remained fairly constant with up to at least 10 cycles. We also investigated electrochemical behavior of thermal products.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 2003
- Accession Number
- ADP014287
Entities
People
- Hong Dong
- M. Whittingham
- Peter Y. Zavalij
- Samuel T. Lutta
Organizations
- Binghamton University