Dynamic Dressing of H+2 in Intense Photon Fields

Abstract

The mechanisms of bond hardening, zero-photon dissociation and orthogonal, counterintuitive alignment that occur when H2(+) ions are exposed to intense femtosecond laser pulses are described in terms of dynamic dressing of the molecular ion system in a photon field. An adiabatic variability is added to the static Floquet picture and the validity of this modification is assessed using the Landau-Zener formula for the probability of non-adiabatic transitions. Application of the dynamic dressing model to the control of chemical reactions is discussed briefly.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2002
Accession Number
ADP015793

Entities

People

  • C. R. Courtney
  • K. Codling
  • L. J. Frasinski

Organizations

  • University of Reading

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Reactions
  • Dissociation
  • Dynamics
  • Energy
  • Energy Gaps
  • Femtosecond Lasers
  • Femtosecond Time
  • Frequency
  • Kinetic Energy
  • Laser Pulses
  • Laser Science
  • Lasers
  • Leading Edges
  • Physics
  • Potential Energy
  • Wave Packets
  • Waves

Fields of Study

  • Physics

Readers

  • Optical Physics and Photonics.
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.
  • Theoretical Analysis.

Technology Areas

  • Directed Energy