Aerobic Biodegradation of DI-n-Butylphthalate by Pure and Mixed Bacterial Species

Abstract

Di-n-butylphthalate (DBP), an organic ester, is primarily used as a plasticizer during the preparation of explosive mixtures. It is abundantly found in the wastewater generated from DBP production plants and munitions manufacturing facilities and at concentrations high enough to create a serious environmental problem. This compound is also listed as a priority pollutant by the USEPA. In this research, the aerobic biodegradation of DBP was studied using several Pseudomonas species as well as mixed bacterial cultures in a batch reactor under suspended growth conditions. The work presented in this paper is part of a broader investigation on the biodegradability of gun propellant components. Initial screening experiments, performed in shaker flasks at 30 degrees C on a gyratory shaker rotating at 200 rpm, indicated that Pseudomonas putida, Pseudomonas resinovorans, and Pseudomonas cepacia can all degrade DBP as a sole carbon source. However, Pseudomonas putida exhibited higher degradation rates compared to the other two species. In addition to pure bacterial species, mixed cultures obtained from an activated sludge system were found to degrade DBP in the absence of any external carbon sources. A number of batch degradation experiments were performed using different initial concentrations of DBP in order to study the rates of degradation of the compound by Pseudomonas putida and activated sludge. The temperature was set at 30 degrees C and the pH was maintained at approximately 7 during the course of the experiment. The higher rate of destruction observed during the kinetic studies suggest that biodegradation is a viable option for the treatment of DBP-containing wastewater.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1996
Accession Number
ADP017729

Entities

People

  • Bruce W. Brodman
  • Christos Christodoulatos
  • Syamalendu Bhaumik

Organizations

  • Stevens Institute of Technology

Tags

Communities of Interest

  • Counter IED
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Aerobic Bacteria
  • Bacteria
  • Biodegradation
  • Bioreactors
  • Calibration
  • Degradation
  • Dental Materials
  • Detection
  • Detectors
  • Double Base Gun Propellants
  • Engineering
  • Environment
  • Environmental Engineering
  • Gun Propellants
  • Microorganisms
  • Phthalates
  • Pseudomonas Infections

Fields of Study

  • Environmental science

Readers

  • Acoustics.
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Environmental Engineering.