Detection system for real-time, experimental characterization/investigation of hot-spots in shocked heterogeneous materials

Abstract

Explosives and propellants consist of energetic crystals embedded in polymeric binders. Thesematerials can be initiated through a variety of stimuli, including thermal, mechanical, and electricalmeans, with the non-thermal stimuli believed to generate heat first which then causes thermallyinduced chemical decomposition. Optimizing the performance of energetic materials for specificapplications has to be balanced against safety and reliability considerations. This process requiresan improved fundamental understanding of chemical decomposition or initiation and relatedtemperature changes.The focus of this project is on developing temperature sensors and then to use these sensors tooptically measure temperature in real time in shocked heterogeneous materials. The temperaturesensors are based on 2-color fluorescence thermometry (2CFT). In 2CFT the fluorescence intensityratio at two emission wavelengths is used to determine the temperature. This approach has beensuccessfully demonstrated using lanthanide ions such as Dy3+ and Sm3+.

Document Details

Document Type
DoD Grant Award
Publication Date
Apr 09, 2018
Source ID
FA95501710381

Entities

People

  • Hergen Eilers

Organizations

  • Air Force Office of Scientific Research
  • United States Air Force
  • Washington State University

Tags

Readers

  • Distributed Systems and Data Platform Development
  • Materials Science and Engineering.
  • Rocket Propulsion.